3. COMPOSITION/INFORMATION ON INGREDIENTS成份辨識資料

此產品為混合物(This product is a mixture)

危害物質成分(HAZARDS INGREDIENTS)

CAS No.

Amount (%W/W )

Sodium hydroxide氫氧化鈉

 

Water treatment; 水質處理劑

 

Water水

1310-73-2

 

6419-19-8

 

7732-18-5

18~28%

 

2~12%

 

60~80%

 

 

4. FIRST AID MEASURES  急救措施

4.1   Eye contact: 眼睛接觸

        -       Rinse immediately with plenty of water for 15 minutes

立刻以大量清水緩和沖洗受污染部位15 分鐘。

        -       If irritation persists consult a doctor/medical service

        任何不適現象持續時請就醫

 

4.2   Skin contact:  肌膚接觸

        -       Wash immediately with lots of water and soap for 15 minutes

        立刻以大量清水緩和沖洗受污染部位15 分鐘。

        -       Remove clothing while washing

        沖洗中脫去衣物

        -       Do not remove clothing if it sticks to the skin

        如果衣服黏附肌膚就不要強行脫去衣物

        -       If irritation persists consult a doctor/medical service

        任何不適現象持續時請就醫

 

4.3   After inhalation: 吸入後處理

        -       Remove the victim into fresh air 移至空曠處呼吸新鮮空氣

        -       Unconscious: maintain adequate airway and respiration

昏迷狀態:請維持適當呼吸

        -       If breathing problems develop: consult a doctor/medical service

        發生呼吸困難:請維持適當呼吸並迅速就醫

4.4   After ingestion: 食用處裡

        -       Immediately after ingestion: give lots of water to drink

        立即飲用大量清水

        -       Never give water to an unconscious person

        不可讓昏迷的人喝水

        -       Allow vomiting 允許催吐 但避免嗆到

        -       If you feel unwell: consult a doctor/medical service

       任何不適現象持續時請就醫

 

5. FIRE FIGHTING MEASURES  滅火措施

5.1   Suitable extinguishing media:

        -       Water spray

        -       Polyvalent foam

        -       Alcohol foam

        -       BC powder

        -       Carbon dioxide

適用滅火劑:噴水、化學乾粉、酒精泡沫、聚合泡沫、二氧化碳。

 

5.2   Special protective equipment for firefighters: 特殊防護裝備

        -       Heat/fire exposure: compressed air/oxygen apparatus of gas-tight suit

        壓縮空氣及氧氣供應設備

 

6. ACCIDENTAL RELEASE MEASURES  洩漏處理方法

Personal Protection 人員防護

Respiratory: Gauze mask. 佩帶薄紗口罩

Eye: Approved safety glasses with side shield. 使用認可的雙邊防護安全眼鏡

Clothes: Protective work clothes. 穿著工作服

Additional Comments: Eye washes and safety showers should be available. 洗眼設備及安全淋浴設備

Educate and train employees in the use of this product, besides also follow all label instructions. 依照指示教育操作人員
 

Environmental Precaution 環境保護預防

Should not be allowed to enter drain or watercourses.

不要讓洩漏物流入下水道
 

Methods for cleaning up 清潔方法

Contain spill with inert material. Absorb in vermiculite, dry sand or earth. Place in the container for disposal according to local regulation.

以不活潑的物質攔截洩漏物。用蛭石、乾砂或泥土吸附。將吸附物置入密閉容器中,依據當地法規棄置。

 

7. HANDLING AND STORAGE  安全處置與儲存方法

Handling

Mechanical ventilation or local exhaust ventilation is required. Avoid all unnecessary.

機械或區域主動式抽氣裝置是必須的。避免任何不必要的搬運或移動。

 

Storage Conditions

Keep contains tightly closed. Keep away from heat and light.

儲存:保持包裝桶密閉。貯存在通風良好,陰涼及陽光無法直接照射的地方,遠離熱、引燃源和不相容物。

 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

暴露預防措施

Exposure Limit Comments 暴露界限

None established.無資料

 

Engineering controls工程控制:

Mechanical ventilation or local exhaust ventilation is required.

1 .單獨使用抗腐蝕的排風系統。2 .排氣口直接通到室外。3.供給充分新鮮空氣以補充排氣系統抽出的空氣。

 

Hand雙手防護

Use protective gloves made of Butyl rubber. 使用丁基橡膠手套。

 

Eye眼部防護

Approved safety glasses with side shield. 使用認可的雙邊防護安全眼鏡
 

Skin and body 肌膚防護

Use suitable protective clothing as protection against splashing or contamination. Launder cloths before re-use. 穿著適當工作服保護操作人員被噴濺到或感染。 工作服再次使用前應清洗。

 

9. PHYSICALAND CHEMICAL PROPERTIES 物理及化學性質

Appearance外觀

Light Red liquid淺紅色液體

Odor味道

ammonia flavors.氨味

NV(Non volatile ingredients) 非揮發性固型份: >30%

H Value(20,0.2): 12.5+_0.5

Non-Flammable不可燃的

Boiling point沸點: >100 oC

Flash point閃火點: N.D. (closed cup)

 

10. STABILITY AND REACTIVITY 安定性及反應性

Thermal decomposition熱分解

No thermal decomposition when stored and handled correctly. 在適當的操作及儲存條件下不會熱分解

 

 

11. TOXICOLOGICAL INFORMATION  毒性資料

Irritation

Skin irritation test(rabbit):corrosive.對皮膚有腐蝕性

Sensitization導致過敏

Non不會

Health effects健康影響

I Skin irritation test(rabbit):corrosive.對皮膚有腐蝕性

 

12. ECOLOGICAL INFORMATION  生態資料

Environmental Fate: (After neutralization中和後)
When released into the soil, this material is not expected to evaporate significantly. When released into the soil, this material may leach into groundwater. When released into the soil, this material may biodegrade to a moderate extent. When released into water, this material is not expected to evaporate significantly. When released into water, this material may biodegrade to a moderate extent. This material has an estimated bioconcentration factor (BCF) of less than 100. This material is not expected to significantly bioaccumulate. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. When released into the air, this material is expected to have a half-life of less than 1 day. 本產品釋放到土壤中,並不會顯著的蒸發。本產品釋放到土壤中,可能會滲透到地下水。本產品釋放到土壤中,會以穩定的速度生物分解。本產品釋放到水中,並不會顯著的蒸發。本產品釋放到水中,會以穩定的速度生物分解。本產品不會生物堆積,其BCF(生物濃縮因數)預期小於100。不會長時間累積在生物體中。本產品釋放到空氣中,會因光照作用快速分解,其半衰期少於1天。
Environmental Toxicity: (After neutralization中和後)
The LC50/96-hour values for fish are over 100 mg/l. This material is not expected to be toxic to aquatic life. 本產品釋放到水中,其96小時對於魚的LC50急毒性,大於100 mg/L。本產品對於水中生物目前未發現毒性。

 

13. DISPOSAL CONSIDERATIONS  廢棄處置方法

Disposal methods

Dispose in safe map in accordance with local/national regulations. Completely empty contents of drums before discarding.空桶廢棄前請確認內容物完全清空。依照當地法令廢棄於安全的地點。

Waste category

Disposal of in accordance with local authority requirements. 依照當地法令廢棄。

 

 

14. TRANSPORT INFORMATION  運送資料

Transportation regulation varies by local.依據當地法令運送。

聯合國編號:1760

聯合國運輸名稱:腐蝕性液體,未另作規定的。

運輸回害分類:8

包裝類別:Ⅲ

海洋污染物:否

特殊規定:223. 274.

 

15. REGULATION INFORMATION 法規資料

勞工安全衛生設施規則

危險物與有害物標示及通識規則

勞工作業環境空氣中有害物容許濃度標準

道路交通安全規則

事業廢棄物貯存清除處理及設施標準

公共危險物品及可燃性高壓氣體設置標準暨安全管理辦法

國際法規

符號 :

R - 類標誌 :

R36 對眼睛有刺激。

S-類標誌句 :

S23 不要吸進噴霧。

S24/25 避免沾及皮膚和眼睛。

S26 如沾入眼睛,立即用大量清水清洗,並盡快就醫診治。

 

16. OTHER INFORMATION 其他

參考文獻 : 行政院勞工委員會 勞工安全衛生處 危險物與有害物標示及通識規則

安全衛生技術中心 Taiwan 2008 GHS Implementation Update

環保署 毒性化學物質標示及物質安全資料表管理辦法

製表單位 : 寶羅國際有限公司

電話: +886 2 27223178

製表人 : 羅寶文

製表日期 : 2013/02/19

與前一版本有較大變化的部分用雙線條表示。

此物質安全資料表提供的資料就本公司所知在其發佈之日是準確無誤的。該資料僅作為安全操作處置、使用、加工、儲存、運輸、廢棄與洩漏等的指導,而不能被作為擔保和品質的指標。以上的資料只適用於此處所指定的特定物質。

對於與其它物質混合使用或此物質被加工過或改變過了的情況,均不適用,除非特別指明。

The information only concerns the above mentioned product as supplied and may not be valid if used with other products or in any process. It remains the user’s own responsibility to make sure that the information is appreciate and complete for the special use of this product.